Redox-active tetrathiafulvalene and dithiolene compounds derived from allylic 1,4-diol rearrangement products of disubstituted 1,3-dithiole derivatives

Redox-active tetrathiafulvalene and dithiolene compounds derived from allylic 1,4-diol rearrangement products of disubstituted 1,3-dithiole derivatives

We present a series of compounds by exploiting the unusual 1,4-aryl shift observed for electron-rich 1,3-dithiole-2-thione and tetrathiafulvalene (TTF) derivatives in the presence of perchloric acid. The mechanistic features of this rearrangement are discussed since this synthetic strategy provides...

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Bibliographic Details
Main Authors: Filipe Vilela, Peter J. Skabara, Christopher R. Mason, Thomas D. J. Westgate, Asun Luquin, Simon J. Coles, Michael B. Hursthouse
Format: Article
Language:English
Published: Beilstein-Institut 2010-10-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
aldehydes
metal-coordination
rearrangement
sulfur heterocycles
tetrathiafulvalene
Online Access:https://doi.org/10.3762/bjoc.6.113

Internet

https://doi.org/10.3762/bjoc.6.113

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