The Role of Different Alkali Metals in the A<sub>15</sub>Tl<sub>27</sub> Type Structure and the Synthesis and X-ray Structure Analysis of a New Substitutional Variant Cs<sub>14.53</sub>Tl<sub>28.4</sub>

The Role of Different Alkali Metals in the A<sub>15</sub>Tl<sub>27</sub> Type Structure and the Synthesis and X-ray Structure Analysis of a New Substitutional Variant Cs<sub>14.53</sub>Tl<sub>28.4</sub>

Alkali metal thallides have been known since the report of E. Zintl on NaTl in 1932. Subsequently, binary and ternary thallides of alkali metals have been characterized. At an alkali metal proportion of approximately 33% (A:Tl~1:2, A = alkali metal), three different unique type structures are report...

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Bibliographic Details
Main Authors: Vanessa F. Schwinghammer, Susanne M. Tiefenthaler, Stefanie Gärtner
Format: Article
Language:English
Published: MDPI AG 2021-12-01
Series:Materials
Subjects:
thallide
intermetallics
single crystal
X-ray structure analysis
Online Access:https://www.mdpi.com/1996-1944/14/24/7512

Internet

https://www.mdpi.com/1996-1944/14/24/7512

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