Influence of vacuum-plasma treatment modes on the surface photo-EMF of single-crystal silicon

Plasma technologies in the last quarter of the twentieth century made a real scientific and technological revolution in microelectronics. Having come to the world of microelectronics technology as a necessary alternative to liquid etching, which had exhausted its resource by that time, plasma or «d...

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Main Authors: R.R. Nagaplezheva, M.M. Orakova, M.Yu. Kushkhova, F.M. Tseeva, H.A. Mishaev
Format: Article
Language:Russian
Published: Tver State University 2022-12-01
Series:Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов
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Online Access:https://physchemaspects.ru/2022/doi-10-26456-pcascnn-2022-14-671/?lang=en
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author R.R. Nagaplezheva
M.M. Orakova
M.Yu. Kushkhova
F.M. Tseeva
H.A. Mishaev
author_facet R.R. Nagaplezheva
M.M. Orakova
M.Yu. Kushkhova
F.M. Tseeva
H.A. Mishaev
author_sort R.R. Nagaplezheva
collection DOAJ
description Plasma technologies in the last quarter of the twentieth century made a real scientific and technological revolution in microelectronics. Having come to the world of microelectronics technology as a necessary alternative to liquid etching, which had exhausted its resource by that time, plasma or «dry» technologies became the main tool for creating elements of electronic products. The 21st century, undoubtedly, began and proceeds under the sign of the improvement of such technologies in solid-state electronics. Plasma technologies include a set of methods for depositing thin and ultrathin layers on a semiconductor substrate, as well as a set of methods for dimensional etching of such layers with specified etching parameters. If we consider the methods of size etching using dry technologies, it should always be taken into account that the whole range of such methods is wide. Some methods, such as radical and plasma-chemical etching, imply a mild, purely chemical interaction of the plasma medium with the substrate material, resulting in the formation of a volatile etch product and its removal (pumping) from the plasma volume. Another group of «dry» methods includes methods of purely physical impact of high-energy plasma particles on the surface of the material and the removal of atoms from the surface only as a result of sputtering of the material. The surface photo-EMF method was used to study the real surface of single-crystal p-type silicon in the temperature range T = 289-473 K before and after plasma treatment. A significant difference was found in the surface electronic states spectra obtained by heating and cooling the samples. Heating leads to desorption of gases and dissociation of water molecules in the surface layer, which reduces the surface potential by an order of magnitude.
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spelling doaj.art-8fa8f00238cc44bcbe43a9c771d5dcf02022-12-22T04:41:44ZrusTver State UniversityФизико-химические аспекты изучения кластеров, наноструктур и наноматериалов2226-44422658-43602022-12-011467167710.26456/pcascnn/2022.14.671Influence of vacuum-plasma treatment modes on the surface photo-EMF of single-crystal siliconR.R. Nagaplezheva0M.M. Orakova1M.Yu. Kushkhova2F.M. Tseeva3H.A. Mishaev4Kabardino-Balkarian State University of H.M. Berbekov, Nalchik, RussiaKabardino-Balkarian State University of H.M. Berbekov, Nalchik, RussiaKabardino-Balkarian State University of H.M. Berbekov, Nalchik, RussiaKabardino-Balkarian State University of H.M. Berbekov, Nalchik, RussiaKabardino-Balkarian State University of H.M. Berbekov, Nalchik, Russia Plasma technologies in the last quarter of the twentieth century made a real scientific and technological revolution in microelectronics. Having come to the world of microelectronics technology as a necessary alternative to liquid etching, which had exhausted its resource by that time, plasma or «dry» technologies became the main tool for creating elements of electronic products. The 21st century, undoubtedly, began and proceeds under the sign of the improvement of such technologies in solid-state electronics. Plasma technologies include a set of methods for depositing thin and ultrathin layers on a semiconductor substrate, as well as a set of methods for dimensional etching of such layers with specified etching parameters. If we consider the methods of size etching using dry technologies, it should always be taken into account that the whole range of such methods is wide. Some methods, such as radical and plasma-chemical etching, imply a mild, purely chemical interaction of the plasma medium with the substrate material, resulting in the formation of a volatile etch product and its removal (pumping) from the plasma volume. Another group of «dry» methods includes methods of purely physical impact of high-energy plasma particles on the surface of the material and the removal of atoms from the surface only as a result of sputtering of the material. The surface photo-EMF method was used to study the real surface of single-crystal p-type silicon in the temperature range T = 289-473 K before and after plasma treatment. A significant difference was found in the surface electronic states spectra obtained by heating and cooling the samples. Heating leads to desorption of gases and dissociation of water molecules in the surface layer, which reduces the surface potential by an order of magnitude. https://physchemaspects.ru/2022/doi-10-26456-pcascnn-2022-14-671/?lang=enplasmaphoto-emfplasma surface treatmentsiliconsurface electronic states
spellingShingle R.R. Nagaplezheva
M.M. Orakova
M.Yu. Kushkhova
F.M. Tseeva
H.A. Mishaev
Influence of vacuum-plasma treatment modes on the surface photo-EMF of single-crystal silicon
Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов
plasma
photo-emf
plasma surface treatment
silicon
surface electronic states
title Influence of vacuum-plasma treatment modes on the surface photo-EMF of single-crystal silicon
title_full Influence of vacuum-plasma treatment modes on the surface photo-EMF of single-crystal silicon
title_fullStr Influence of vacuum-plasma treatment modes on the surface photo-EMF of single-crystal silicon
title_full_unstemmed Influence of vacuum-plasma treatment modes on the surface photo-EMF of single-crystal silicon
title_short Influence of vacuum-plasma treatment modes on the surface photo-EMF of single-crystal silicon
title_sort influence of vacuum plasma treatment modes on the surface photo emf of single crystal silicon
topic plasma
photo-emf
plasma surface treatment
silicon
surface electronic states
url https://physchemaspects.ru/2022/doi-10-26456-pcascnn-2022-14-671/?lang=en
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