Tetra-μ3-selenido-1:2:3κ3Se;1:2:4κ3Se;1:3:4κ3Se;2:3:4κ3Se-tetrakis[(η5-methylcyclopentadienyl)molybdenum(III)](6 Mo—Mo)

The title cluster compound, [Mo4(η5-C5H4Me)4(μ3-Se)4], was synthesized from the reaction of [Mo(η5-C5H4Me)(CO)3]2 with grey selenium in refluxing xylene solution under a nitrogen atmosphere. The complete cluster is generated by a crystallographic twofold axis and contains an Mo4Se4 cubane-like core...

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Bibliographic Details
Main Authors: Akito Ouchi, Tsugiko Takase, Shinji Inomata
Format: Article
Language:English
Published: International Union of Crystallography 2023-08-01
Series:IUCrData
Subjects:
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314623006570