EPR and electrochemistry of [NH4]trans-[RuCl4(DMSO)(L)] complexes (L = DMSO, py ). X-ray molecular structure of [pyH][RuCl4(DMSO)(py)]

EPR and electrochemistry of [NH4]trans-[RuCl4(DMSO)(L)] complexes (L = DMSO, py ). X-ray molecular structure of [pyH][RuCl4(DMSO)(py)]

The [(DMSO)2H]trans-[RuCl4 (DMSO)2] complex presents an axial symmetry in the solid state and its EPR spectrum shows two g values (g<FONT FACE="Symbol">&#094;</FONT > or = 2,35 e g<FONT FACE="Symbol">//</FONT > or = 1,87). The complex [NH4]trans-[RuCl4...

Full description

Bibliographic Details
Main Authors: Paula Quêite A. de, Batista Alzir A., Nascimento Otaciro R., Costa-Filho Antônio J. da, Schultz Mário S., Bonfadini Marcos R., Oliva Glaucius
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2000-01-01
Series:Journal of the Brazilian Chemical Society
Subjects:
EPR
cyclic voltammetry
tetrachlororuthenate(III)
X-ray structure analyses
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000500016

Internet

http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000500016

Similar Items