Ammonia Uptake and Release in the MnX2–NH3 (X = Cl, Br) Systems and Structure of the Mn(NH3)nX2 (n = 6, 2) Ammines

Ammonia Uptake and Release in the MnX2–NH3 (X = Cl, Br) Systems and Structure of the Mn(NH3)nX2 (n = 6, 2) Ammines

Hexa-ammine complexes, Mn(NH3)6X2 (X = Cl, Br), have been synthesized by ammoniation of the corresponding transition metal halide and characterized by Powder X-ray diffraction (PXRD) and Raman spectroscopy. The hexa-ammine complexes are isostructural (Cubic, Fm-3m, Z = 4; a = 10.2742(6) Å and 10.527...

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Bibliographic Details
Main Authors: Duncan H. Gregory, Imogen Fullbrook, Michael Grant, James M. Hanlon, Hazel Reardon
Format: Article
Language:English
Published: MDPI AG 2012-04-01
Series:Crystals
Subjects:
manganese
ammines
chloride
bromide
structure
Raman
ammonia storage
hydrogen storage
Online Access:http://www.mdpi.com/2073-4352/2/2/193

Internet

http://www.mdpi.com/2073-4352/2/2/193

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