Two in one: the bismuth bromido clusters in [Bi6Cp*6Br9][Bi7Br24]
The reaction of [FeCp*(CO)2]2 in CH2Cl2 with BiBr3 in a 1:1 molar ratio gave the novel bismuth compound [Bi6Cp*6Br9][Bi7Br24] (1), which is composed of a cationic and an anionic bismuth bromido cluster: the cation is based on a hexanuclear bismuth {Bi6}-octahedron and the anion showing the first hep...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
De Gruyter
2014-12-01
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| Series: | Main Group Metal Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/mgmc-2014-0036 |