Evidence of Many-Body Interactions in the Virial Coefficients of Polyelectrolyte Gels

Simulation studies of aqueous polymer solutions, and heuristic arguments by De Gennes for aqueous polyethylene oxide polymer solutions, have suggested that many-body interactions can give rise to the ‘anomalous’ situation in which the second osmotic virial coefficient is positive, while the third vi...

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Bibliographic Details
Main Authors: Ferenc Horkay, Jack F. Douglas
Format: Article
Language:English
Published: MDPI AG 2022-02-01
Series:Gels
Subjects:
Online Access:https://www.mdpi.com/2310-2861/8/2/96