Novel partially cross-linked nanoparticles graft co-polymer as pore former for polyethersulfone membranes for dyes removal
A newly developed water-soluble polymeric nano-additive termed “partially cross-linked nanoparticles graft copolymer (PCLNPG)'' has been successfully synthesized and harnessed as a pore former for modifying a polyethersulfone ultrafiltration membrane for dyes removal. The PCLNPG content wa...
| Main Authors: | , , , , , , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2023-11-01
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| Series: | Heliyon |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2405844023091661 |
| _version_ | 1827615880970764288 |
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| author | Kadhum M. Shabeeb Wallaa A. Noori Ali A. Abdulridha Hasan Sh Majdi Mohammad N. Al-Baiati Ali A. Yahya Khalid T. Rashid Zoltán Németh Klara Hernadi Qusay F. Alsalhy |
| author_facet | Kadhum M. Shabeeb Wallaa A. Noori Ali A. Abdulridha Hasan Sh Majdi Mohammad N. Al-Baiati Ali A. Yahya Khalid T. Rashid Zoltán Németh Klara Hernadi Qusay F. Alsalhy |
| author_sort | Kadhum M. Shabeeb |
| collection | DOAJ |
| description | A newly developed water-soluble polymeric nano-additive termed “partially cross-linked nanoparticles graft copolymer (PCLNPG)'' has been successfully synthesized and harnessed as a pore former for modifying a polyethersulfone ultrafiltration membrane for dyes removal. The PCLNPG content was varied in the PES polymeric matrix aiming to scrutinize its impact on membrane surface characteristics, morphological structure, and overall performance. Proposed interaction mechanism between methylene blue (MB), methyle orange (MO), and malachite green (MG) dyes with PES membrane was presented as well. Hydrophilicity and porosity of the novel membrane increased by 18 and 17 %, respectively, when manufactured with a 3 Wt. % PCLNPG, according to the findings. Besides this, the disclosed increased porosity, rather than the hydrophilic properties of the water-soluble PCLNPG, was the principal cause of the diminished contact angle. Meanwhile, raising the PCLNPG content in the prepared membrane made worthy shifts in its structure. A sponge-like region was materialized near the bottom surface as well. The membrane's pure water flux (PWF) synthesized with 3 Wt.% PCLNPG recorded 628 LMH, which is estimated 3.95 fold the pristine membrane. MG, MB, and MO dyes were rejected by 90.6, 96.3, and 97.87 %, respectively. These findings showed that the performance characteristics of the PES/PCLNPG membrane make it a potentially advantageous option to treat the textile wastewater. |
| first_indexed | 2024-03-09T09:17:58Z |
| format | Article |
| id | doaj.art-94451f08a5a14d8aa233a2bfabf8cdca |
| institution | Directory Open Access Journal |
| issn | 2405-8440 |
| language | English |
| last_indexed | 2024-03-09T09:17:58Z |
| publishDate | 2023-11-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Heliyon |
| spelling | doaj.art-94451f08a5a14d8aa233a2bfabf8cdca2023-12-02T07:04:46ZengElsevierHeliyon2405-84402023-11-01911e21958Novel partially cross-linked nanoparticles graft co-polymer as pore former for polyethersulfone membranes for dyes removalKadhum M. Shabeeb0Wallaa A. Noori1Ali A. Abdulridha2Hasan Sh Majdi3Mohammad N. Al-Baiati4Ali A. Yahya5Khalid T. Rashid6Zoltán Németh7Klara Hernadi8Qusay F. Alsalhy9Department of Materials Engineering, University of Technology- Iraq, Alsinaa Street 52, 10066 Baghdad, IraqMembrane Technology Research Unit, Chemical Engineering Department, University of Technology- Iraq, Alsinaa Street 52, 10066 Baghdad, IraqDepartment of Pharmacy, Alsafwa University College, Karbala, IraqDepartment of Chemical Engineering and Petroleum Industries, Al-Mustaqbal University, Babylon, 51001, IraqDepartment of Chemistry, College of Education for Pure Sciences, University of Kerbala, 56001, Kerbala, IraqMembrane Technology Research Unit, Chemical Engineering Department, University of Technology- Iraq, Alsinaa Street 52, 10066 Baghdad, IraqMembrane Technology Research Unit, Chemical Engineering Department, University of Technology- Iraq, Alsinaa Street 52, 10066 Baghdad, IraqAdvanced Materials and Intelligent Technologies Higher Education and Industrial Cooperation Centre, University of Miskolc, H-3515, Miskolc, HungaryAdvanced Materials and Intelligent Technologies Higher Education and Industrial Cooperation Centre, University of Miskolc, H-3515, Miskolc, HungaryMembrane Technology Research Unit, Chemical Engineering Department, University of Technology- Iraq, Alsinaa Street 52, 10066 Baghdad, Iraq; Corresponding author.A newly developed water-soluble polymeric nano-additive termed “partially cross-linked nanoparticles graft copolymer (PCLNPG)'' has been successfully synthesized and harnessed as a pore former for modifying a polyethersulfone ultrafiltration membrane for dyes removal. The PCLNPG content was varied in the PES polymeric matrix aiming to scrutinize its impact on membrane surface characteristics, morphological structure, and overall performance. Proposed interaction mechanism between methylene blue (MB), methyle orange (MO), and malachite green (MG) dyes with PES membrane was presented as well. Hydrophilicity and porosity of the novel membrane increased by 18 and 17 %, respectively, when manufactured with a 3 Wt. % PCLNPG, according to the findings. Besides this, the disclosed increased porosity, rather than the hydrophilic properties of the water-soluble PCLNPG, was the principal cause of the diminished contact angle. Meanwhile, raising the PCLNPG content in the prepared membrane made worthy shifts in its structure. A sponge-like region was materialized near the bottom surface as well. The membrane's pure water flux (PWF) synthesized with 3 Wt.% PCLNPG recorded 628 LMH, which is estimated 3.95 fold the pristine membrane. MG, MB, and MO dyes were rejected by 90.6, 96.3, and 97.87 %, respectively. These findings showed that the performance characteristics of the PES/PCLNPG membrane make it a potentially advantageous option to treat the textile wastewater.http://www.sciencedirect.com/science/article/pii/S2405844023091661NanoparticlesGraft co-polymerTextileDye removalUltrafiltrationMembrane fouling |
| spellingShingle | Kadhum M. Shabeeb Wallaa A. Noori Ali A. Abdulridha Hasan Sh Majdi Mohammad N. Al-Baiati Ali A. Yahya Khalid T. Rashid Zoltán Németh Klara Hernadi Qusay F. Alsalhy Novel partially cross-linked nanoparticles graft co-polymer as pore former for polyethersulfone membranes for dyes removal Heliyon Nanoparticles Graft co-polymer Textile Dye removal Ultrafiltration Membrane fouling |
| title | Novel partially cross-linked nanoparticles graft co-polymer as pore former for polyethersulfone membranes for dyes removal |
| title_full | Novel partially cross-linked nanoparticles graft co-polymer as pore former for polyethersulfone membranes for dyes removal |
| title_fullStr | Novel partially cross-linked nanoparticles graft co-polymer as pore former for polyethersulfone membranes for dyes removal |
| title_full_unstemmed | Novel partially cross-linked nanoparticles graft co-polymer as pore former for polyethersulfone membranes for dyes removal |
| title_short | Novel partially cross-linked nanoparticles graft co-polymer as pore former for polyethersulfone membranes for dyes removal |
| title_sort | novel partially cross linked nanoparticles graft co polymer as pore former for polyethersulfone membranes for dyes removal |
| topic | Nanoparticles Graft co-polymer Textile Dye removal Ultrafiltration Membrane fouling |
| url | http://www.sciencedirect.com/science/article/pii/S2405844023091661 |
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