Cobalt(II) Terpyridin-4′-yl Nitroxide Complex as an Exchange-Coupled Spin-Crossover Material
Spin-crossover (SCO) was studied in [Co(L)2](CF3SO3)2, where L stands for diamagnetic 2,2′:6′,2′′-terpyridine (tpy) and its paramagnetic derivative, 4′-{4-tert-butyl(N-oxy)aminophenyl}-substituted tpy (tpyphNO). The X-ray crystallographic analysis clarified the Co-N bond length change (Δd) in high-...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2018-04-01
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| Series: | Crystals |
| Subjects: | |
| Online Access: | http://www.mdpi.com/2073-4352/8/4/155 |