Association of Halogen Bonding and Hydrogen Bonding in Metal Acetate-Catalyzed Asymmetric Halolactonization

Association of Halogen Bonding and Hydrogen Bonding in Metal Acetate-Catalyzed Asymmetric Halolactonization

Summary: Cooperative activation using halogen bonding and hydrogen bonding works in metal-catalyzed asymmetric halolactonization. The Zn3(OAc)4-3,3′-bis(aminoimino)binaphthoxide (tri-Zn) complex catalyzes both asymmetric iodolactonization and bromolactonization. Carboxylic acid substrates are conver...

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Bibliographic Details
Main Authors: Takayoshi Arai, Kodai Horigane, Ohji Watanabe, Junki Kakino, Noriyuki Sugiyama, Hiroki Makino, Yuto Kamei, Shinnosuke Yabe, Masahiro Yamanaka
Format: Article
Language:English
Published: Elsevier 2019-02-01
Series:iScience
Online Access:http://www.sciencedirect.com/science/article/pii/S2589004219300318

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http://www.sciencedirect.com/science/article/pii/S2589004219300318

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