A combined experimental and computational study of ligand-controlled Chan-Lam coupling of sulfenamides

Abstract The unique features of the sulfenamides’ S(II)-N bond lead to interesting stereochemical properties and significant industrial functions. Here we present a chemoselective Chan–Lam coupling of sulfenamides to prepare N-arylated sulfenamides. A tridentate pybox ligand governs the chemoselecti...

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Bibliographic Details
Main Authors: Kaiming Han, Hong Liu, Madeline E. Rotella, Zeyu Xu, Lizhi Tao, Shufeng Chen, Marisa C. Kozlowski, Tiezheng Jia
Format: Article
Language:English
Published: Nature Portfolio 2024-06-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-024-49089-0