Synthesis and Reactivity of a Cerium(III) Scorpionate Complex Containing a Redox Non-Innocent 2,2′-Bipyridine Ligand
The Ce(III) hydrotris(3,5-dimethylpyrazolyl)borate complex [Ce(TpMe2)2(κ2-dmpz)] (1) (TpMe2 = {HB(dmpz)3}−; dmpz = 3,5-dimethylpyrazolide) was isolated in fair yield from the reaction of [Ce(I)3(THF)4] with two equivalents of [K(TpMe2)] via the facile decomposition of TpMe2. [Ce(TpMe2)2(bipy)] (2) w...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2015-11-01
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| Series: | Inorganics |
| Subjects: | |
| Online Access: | http://www.mdpi.com/2304-6740/3/4/534 |