Crystal structures of two isotypic lanthanide(III) complexes: triaqua[2,6-diacetylpyridine bis(benzoylhydrazone)]methanollanthanide(III) trichloride methanol disolvates (LnIII = Tb and Dy)

Crystal structures of two isotypic lanthanide(III) complexes: triaqua[2,6-diacetylpyridine bis(benzoylhydrazone)]methanollanthanide(III) trichloride methanol disolvates (LnIII = Tb and Dy)

The title lanthanide complexes, [Ln(DAPBH2)(CH3OH)(H2O)3]Cl3·2CH3OH [LnIII = Tb and Dy; DAPBH2 = 2,6-diacetylpyridine bis(benzoylhydrazone), C23H21N5O2], are isotypic. The central lanthanide ions are nine-coordinate, being ligated by three N and two O atoms from the pentadentate DAPBH2 ligand, and f...

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Bibliographic Details
Main Authors: Chihiro Kachi-Terajima, Norihisa Kimura
Format: Article
Language:English
Published: International Union of Crystallography 2018-04-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
lanthanide(III)
2,6-diacetylpyridine bis(benzoylhydrazone) ligand
terbium(II)
dysprosium (III)
hydrogen bonding
π–π stacking
supramolecular framework
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989018004103

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http://scripts.iucr.org/cgi-bin/paper?S2056989018004103

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