A “Pretender” Croconate-Bridged Macrocyclic Tetraruthenium Complex: Sizable Redox Potential Splittings despite Electronically Insulated Divinylphenylene Diruthenium Entities

A “Pretender” Croconate-Bridged Macrocyclic Tetraruthenium Complex: Sizable Redox Potential Splittings despite Electronically Insulated Divinylphenylene Diruthenium Entities

Careful optimization of the reaction conditions provided access to the particularly small tetraruthenium macrocycle <b><sup>2</sup>Ru<sub>2</sub>Ph-Croc</b>, which is composed out of two redox-active divinylphenylene-bridged diruthenium entities {Ru}-1,4-CH=CH-C&l...

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Bibliographic Details
Main Authors: Nils Rotthowe, Michael Linseis, Lars Vogelsang, Nicole Orth, Ivana Ivanović-Burmazović, Rainer F. Winter
Format: Article
Language:English
Published: MDPI AG 2021-08-01
Series:Molecules
Subjects:
metallamacrocycle
electrochemistry
spectroelectrochemistry
crystal structure
redox splitting
Online Access:https://www.mdpi.com/1420-3049/26/17/5232

Internet

https://www.mdpi.com/1420-3049/26/17/5232

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