Ionothermal Synthesis of Sulfidobismuth spiro‐Dicubane Cations

Ionothermal Synthesis of Sulfidobismuth spiro‐Dicubane Cations

Abstract Bi2S3 was dissolved in the presence of NaCl in the ionic liquid [BMIm]Cl ⋅ 4AlCl3 (BMIm=1‐n‐butyl‐3‐methylimidazolium) through annealing the mixture at 180 °C. Upon cooling to room temperature, orange, air‐sensitive crystals of Na(Bi7S8)[S(AlCl3)3]2[AlCl4]2 (1) precipitated. X‐ray diffracti...

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Bibliographic Details
Main Authors: Maximilian Knies, Prof. Dr. Michael Ruck
Format: Article
Language:English
Published: Wiley-VCH 2022-02-01
Series:ChemistryOpen
Subjects:
bismuth
heterocubanes
ionic liquids
ionothermal synthesis
spirocubanes
Online Access:https://doi.org/10.1002/open.202100145

Internet

https://doi.org/10.1002/open.202100145

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