Ionothermal Synthesis of Sulfidobismuth spiro‐Dicubane Cations
Abstract Bi2S3 was dissolved in the presence of NaCl in the ionic liquid [BMIm]Cl ⋅ 4AlCl3 (BMIm=1‐n‐butyl‐3‐methylimidazolium) through annealing the mixture at 180 °C. Upon cooling to room temperature, orange, air‐sensitive crystals of Na(Bi7S8)[S(AlCl3)3]2[AlCl4]2 (1) precipitated. X‐ray diffracti...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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Wiley-VCH
2022-02-01
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| Series: | ChemistryOpen |
| Subjects: | |
| Online Access: | https://doi.org/10.1002/open.202100145 |
| _version_ | 1830403075269984256 |
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| author | Maximilian Knies Prof. Dr. Michael Ruck |
| author_facet | Maximilian Knies Prof. Dr. Michael Ruck |
| author_sort | Maximilian Knies |
| collection | DOAJ |
| description | Abstract Bi2S3 was dissolved in the presence of NaCl in the ionic liquid [BMIm]Cl ⋅ 4AlCl3 (BMIm=1‐n‐butyl‐3‐methylimidazolium) through annealing the mixture at 180 °C. Upon cooling to room temperature, orange, air‐sensitive crystals of Na(Bi7S8)[S(AlCl3)3]2[AlCl4]2 (1) precipitated. X‐ray diffraction on single‐crystals of 1 revealed a triclinic crystal structure that contains (Bi7S8)5+ spiro‐dicubanes, [S(AlCl3)3]2− tetrahedra triples, isolated [AlCl4]− tetrahedra, and sodium cations. |
| first_indexed | 2024-12-20T17:02:16Z |
| format | Article |
| id | doaj.art-9727400092214843800a1f841bbaba48 |
| institution | Directory Open Access Journal |
| issn | 2191-1363 |
| language | English |
| last_indexed | 2024-12-20T17:02:16Z |
| publishDate | 2022-02-01 |
| publisher | Wiley-VCH |
| record_format | Article |
| series | ChemistryOpen |
| spelling | doaj.art-9727400092214843800a1f841bbaba482022-12-21T19:32:28ZengWiley-VCHChemistryOpen2191-13632022-02-01112n/an/a10.1002/open.202100145Ionothermal Synthesis of Sulfidobismuth spiro‐Dicubane CationsMaximilian Knies0Prof. Dr. Michael Ruck1Faculty of Chemistry and Food Chemistry Technische Universität Dresden 01069 Dresden GermanyFaculty of Chemistry and Food Chemistry Technische Universität Dresden 01069 Dresden GermanyAbstract Bi2S3 was dissolved in the presence of NaCl in the ionic liquid [BMIm]Cl ⋅ 4AlCl3 (BMIm=1‐n‐butyl‐3‐methylimidazolium) through annealing the mixture at 180 °C. Upon cooling to room temperature, orange, air‐sensitive crystals of Na(Bi7S8)[S(AlCl3)3]2[AlCl4]2 (1) precipitated. X‐ray diffraction on single‐crystals of 1 revealed a triclinic crystal structure that contains (Bi7S8)5+ spiro‐dicubanes, [S(AlCl3)3]2− tetrahedra triples, isolated [AlCl4]− tetrahedra, and sodium cations.https://doi.org/10.1002/open.202100145bismuthheterocubanesionic liquidsionothermal synthesisspirocubanes |
| spellingShingle | Maximilian Knies Prof. Dr. Michael Ruck Ionothermal Synthesis of Sulfidobismuth spiro‐Dicubane Cations ChemistryOpen bismuth heterocubanes ionic liquids ionothermal synthesis spirocubanes |
| title | Ionothermal Synthesis of Sulfidobismuth spiro‐Dicubane Cations |
| title_full | Ionothermal Synthesis of Sulfidobismuth spiro‐Dicubane Cations |
| title_fullStr | Ionothermal Synthesis of Sulfidobismuth spiro‐Dicubane Cations |
| title_full_unstemmed | Ionothermal Synthesis of Sulfidobismuth spiro‐Dicubane Cations |
| title_short | Ionothermal Synthesis of Sulfidobismuth spiro‐Dicubane Cations |
| title_sort | ionothermal synthesis of sulfidobismuth spiro dicubane cations |
| topic | bismuth heterocubanes ionic liquids ionothermal synthesis spirocubanes |
| url | https://doi.org/10.1002/open.202100145 |
| work_keys_str_mv | AT maximilianknies ionothermalsynthesisofsulfidobismuthspirodicubanecations AT profdrmichaelruck ionothermalsynthesisofsulfidobismuthspirodicubanecations |