Crystal structure of bromidopentakis(tetrahydrofuran-κO)magnesium bis[1,2-bis(diphenylphosphanyl)benzene-κ2P,P′]cobaltate(−1) tetrahydrofuran disolvate

Crystal structure of bromidopentakis(tetrahydrofuran-κO)magnesium bis[1,2-bis(diphenylphosphanyl)benzene-κ2P,P′]cobaltate(−1) tetrahydrofuran disolvate

Structural characterization of the ionic title complex, [MgBr(THF)5][Co(dpbz)2]·2THF [THF is tetrahydrofuran, C4H8O; dpbz is 1,2-bis(diphenylphosphanyl)benzene, C30H24P2], revealed a well-separated cation and anion co-crystallized with two THF solvent molecules that interact with the cation via weak...

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Bibliographic Details
Main Authors: Patience B. Girigiri, Stephanie H. Carpenter, William W. Brennessel, Michael L. Neidig
Format: Article
Language:English
Published: International Union of Crystallography 2019-02-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
cobalt
1,2-bis(diphenylphosphanyl)benzene
bidentate phosphane
bisphosphane
pseudotetrahedral
backbonding
crystal structure
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989019001671

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http://scripts.iucr.org/cgi-bin/paper?S2056989019001671

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