Halogen Bond-Involving Self-Assembly of Iodonium Carboxylates: Adding a Dimension to Supramolecular Architecture

Halogen Bond-Involving Self-Assembly of Iodonium Carboxylates: Adding a Dimension to Supramolecular Architecture

We designed 0D, 1D, and 2D supramolecular assemblies made of diaryliodonium salts (functioning as double σ-hole donors) and carboxylates (as σ-hole acceptors). The association was based on two charge-supported halogen bonds (XB), which occurred between I<sup>III</sup> sites of the iodoni...

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Bibliographic Details
Main Authors: Amirbek D. Radzhabov, Alyona I. Ledneva, Natalia S. Soldatova, Irina I. Fedorova, Daniil M. Ivanov, Alexey A. Ivanov, Mekhman S. Yusubov, Vadim Yu. Kukushkin, Pavel S. Postnikov
Format: Article
Language:English
Published: MDPI AG 2023-09-01
Series:International Journal of Molecular Sciences
Subjects:
halogen bond
diaryliodonium salt
carboxylate
supramolecular assembly
DFT calculations
Online Access:https://www.mdpi.com/1422-0067/24/19/14642

Internet

https://www.mdpi.com/1422-0067/24/19/14642

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