A New Charge-Ordered Molecular Conductor: <i>κ</i>-(BEDT-TTF)<sub>2</sub>K<sup>+</sup>(18-crown-6)[Co<sup>II</sup>(NCS)<sub>4</sub>]∙(H<sub>2</sub>O)

A New Charge-Ordered Molecular Conductor: <i>κ</i>-(BEDT-TTF)<sub>2</sub>K<sup>+</sup>(18-crown-6)[Co<sup>II</sup>(NCS)<sub>4</sub>]∙(H<sub>2</sub>O)

A new molecular conductor, i.e., <i>κ</i>-(BEDT-TTF)<sub>2</sub>K<sup>+</sup>(18-crown-6)[Co<sup>II</sup>(NCS)<sub>4</sub>]∙(H<sub>2</sub>O), is semiconductive with substantial charge gap values (Δ<i>E</i>) of 0.57 e...

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Bibliographic Details
Main Authors: Andrei A. Bardin, Tatiana G. Prokhorova, Lev I. Buravov
Format: Article
Language:English
Published: MDPI AG 2023-10-01
Series:Crystals
Subjects:
single-molecule magnet (SMM)
charge ordering (CO)
stripe order
metal-insulator (MI) transition
molecular conductors
electrocrystallization
Online Access:https://www.mdpi.com/2073-4352/13/10/1504

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https://www.mdpi.com/2073-4352/13/10/1504

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