Ligand Chirality Transfer from Solution State to the Crystalline Self‐Assemblies in Circularly Polarized Luminescence (CPL) Active Lanthanide Systems

Ligand Chirality Transfer from Solution State to the Crystalline Self‐Assemblies in Circularly Polarized Luminescence (CPL) Active Lanthanide Systems

Abstract The synthesis of a family of chiral and enantiomerically pure pyridyl‐diamide (pda) ligands that upon complexation with europium [Eu(CF3SO3)3] result in chiral complexes with metal centered luminescence is reported; the sets of enantiomers giving rise to both circular dichroism (CD) and cir...

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Bibliographic Details
Main Authors: David F. Caffrey, Tumpa Gorai, Bláithín Rawson, Miguel Martínez‐Calvo, Jonathan A. Kitchen, Niamh S. Murray, Oxana Kotova, Steve Comby, Robert D. Peacock, Patrycja Stachelek, Robert Pal, Thorfinnur Gunnlaugsson
Format: Article
Language:English
Published: Wiley 2024-05-01
Series:Advanced Science
Subjects:
circularly polarized luminescence (CPL)
coordination chemistry
lanthanide luminescence
pyridyl‐diamide (pda)
self‐assembly
Online Access:https://doi.org/10.1002/advs.202307448

Internet

https://doi.org/10.1002/advs.202307448

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