Inclusion of the insecticide fenitrothion in dimethylated-β-cyclodextrin: unusual guest disorder in the solid state and efficient retardation of the hydrolysis rate of the complexed guest in alkaline solution

Inclusion of the insecticide fenitrothion in dimethylated-β-cyclodextrin: unusual guest disorder in the solid state and efficient retardation of the hydrolysis rate of the complexed guest in alkaline solution

An anhydrous 1:1 crystalline inclusion complex between the organophosphorus insecticide fenitrothion [O,O-dimethyl O-(3-methyl-4-nitrophenyl)phosphorothioate] and the host compound heptakis(2,6-di-O-methyl)-β-cyclodextrin (DIMEB) was prepared and its structure elucidated by single-crystal X-ray diff...

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Bibliographic Details
Main Authors: Dyanne L. Cruickshank, Natalia M. Rougier, Raquel V. Vico, Susan A. Bourne, Elba I. Buján, Mino R. Caira, Rita H. de Rossi
Format: Article
Language:English
Published: Beilstein-Institut 2013-01-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
crystal structure
cyclodextrin
fenitrothion
hydrolysis
inclusion complex
Online Access:https://doi.org/10.3762/bjoc.9.14

Internet

https://doi.org/10.3762/bjoc.9.14

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