Cyclic Carbonates through the Photo-Induced Carboxylative Cyclization of Allylic Alcohol with CO<sub>2</sub>: A Comprehensive Kinetic Study of the Reaction Mechanism by In Situ ATR-IR Spectroscopy
A one-pot multicomponent green process is investigated for the synthesis of perfluoroalkylated cyclic carbonate which merges the photo-promoted Atom Transfer Radical Addition (ATRA) of a perfluoroalkyl iodide (Rf-I) onto allyl alcohols with the Lewis-base-promoted carboxylative cyclization. The evol...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2023-05-01
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| Series: | Catalysts |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2073-4344/13/6/939 |