Preparations of <i>trans</i>- and <i>cis</i>-<i>μ</i>-1,2-Peroxodiiron(III) Complexes

Preparations of <i>trans</i>- and <i>cis</i>-<i>μ</i>-1,2-Peroxodiiron(III) Complexes

The iron(II) complex with <i>cis,cis</i>-1,3,5-tris(benzylamino)cyclohexane (Bn<sub>3</sub>CY) (<b>1</b>) has been synthesized and characterized, which reacted with dioxygen to form the peroxo complex <b>2</b> in acetone at −60 °C. On the basis of spec...

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Bibliographic Details
Main Authors: Yuji Kajita, Masaki Kubo, Hidekazu Arii, Shinya Ishikawa, Yamato Saito, Yuko Wasada-Tsutsui, Yasuhiro Funahashi, Tomohiro Ozawa, Hideki Masuda
Format: Article
Language:English
Published: MDPI AG 2023-12-01
Series:Molecules
Subjects:
<i>cis</i>-<i>μ</i>-1,2-peroxodiiron complex
<i>trans</i>-<i>μ</i>-1,2-peroxodiiron complex
resonance Raman spectrum
X-ray crystal structure
DFT calculation
Online Access:https://www.mdpi.com/1420-3049/29/1/205

Internet

https://www.mdpi.com/1420-3049/29/1/205

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