Crystal structures of [IrCl2(NHCHPh)((dppm)(C(N2dppm))-κ3P,C,P′)]Cl·5.5MeCN and [IrI(NHCHPh)(((dppm)C(N2))-κ2P,C)(dppm-κ2P,P′)]I(I3)·0.5I2·MeOH·0.5CH2Cl2: triazene fragmentation in a PCN pincer iridium complex

Crystal structures of [IrCl2(NHCHPh)((dppm)(C(N2dppm))-κ3P,C,P′)]Cl·5.5MeCN and [IrI(NHCHPh)(((dppm)C(N2))-κ2P,C)(dppm-κ2P,P′)]I(I3)·0.5I2·MeOH·0.5CH2Cl2: triazene fragmentation in a PCN pincer iridium complex

The structure of [IrCl2(C58H51N3P4)]Cl·5.5CH3CN or [IrCl2(NHCHPh)(((dppm)C(N2dppm))-κ3P,C,P)]Cl·5.5CH3CN [3, dppm = bis(diphenylphosphino)methane; systematic name: dichlorido(1,1,3,3,7,7,9,9-octaphenyl-4,5-diaza-1,3λ5,7λ4,9-tetraphosphanona-3,5-dien-6-yl-κ2P1,P9)(phenylmethanimine-κN)iridium(III) ch...

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Bibliographic Details
Main Authors: Bettina Pauer, Gabriel Julian Partl, Stefan Oberparleiter, Walter Schuh, Holger Kopacka, Klaus Wurst, Paul Peringer
Format: Article
Language:English
Published: International Union of Crystallography 2019-02-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
carbodiphosphorane
divalent carbon
triazene
fragmentation
diazomethylenephosphorane
diazophosphorane
nitrene
iridium(III)
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989019000136

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http://scripts.iucr.org/cgi-bin/paper?S2056989019000136

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