Nickel-catalyzed acylzincation of allenes with organozincs and CO

Abstract Transition metal-catalyzed carbonylative reaction with CO gas are among the central task in organic synthesis, enabling the construction of highly valuable carbonyl compound. Here, we show an earth-abundant nickel-catalyzed three-component tandem acylzincation/cyclization sequence of allene...

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Bibliographic Details
Main Authors: Xianqing Wu, Chenglong Wang, Ning Liu, Jingping Qu, Yifeng Chen
Format: Article
Language:English
Published: Nature Portfolio 2023-10-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-023-42716-2