Rhodium-Catalyzed Dynamic Kinetic Resolution of Racemic Internal Allenes towards Chiral Allylated Triazoles and Tetrazoles

Rhodium-Catalyzed Dynamic Kinetic Resolution of Racemic Internal Allenes towards Chiral Allylated Triazoles and Tetrazoles

A general Rh-catalyzed addition reaction of nitrogen containing heterocycles to internal allenes is reported. Starting from racemic internal allenes a dynamic kinetic resolution (DKR) provides <i>N</i>-allylated triazoles and tetrazoles. Simultaneous control of <i>N</i><su...

Full description

Bibliographic Details
Main Authors: Simon V. Sieger, Ilja Lubins, Bernhard Breit
Format: Article
Language:English
Published: MDPI AG 2022-10-01
Series:Catalysts
Subjects:
asymmetric catalysis
dynamic kinetic resolution
internal allenes
rhodium
hydroamination
Online Access:https://www.mdpi.com/2073-4344/12/10/1209

Internet

https://www.mdpi.com/2073-4344/12/10/1209

Similar Items