Electrochemical and Optical Spectroscopic Probing of Transition‐Sized Au130(SR)50 Nanoclusters
Abstract Ultrasmall metal nanoclusters (NCs) exhibit a quantized conduction band, hence, a distinct HOMO‐LUMO gap (Eg). Such a quantized electronic structure gives rise to multiple discrete peaks in the optical absorption spectrum of the NCs. As the size grows to 130 gold atoms (Au130 protected by l...
| Main Authors: | , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley-VCH
2024-04-01
|
| Series: | ChemElectroChem |
| Online Access: | https://doi.org/10.1002/celc.202300528 |