Mechanistic Details of the Sharpless Epoxidation of Allylic Alcohols—A Combined URVA and Local Mode Study

In this work, we investigated the catalytic effects of a Sharpless dimeric titanium (IV)–tartrate–diester catalyst on the epoxidation of allylalcohol with methyl–hydroperoxide considering four different orientations of the reacting species coordinated at the titanium atom (reactions <b>R1</...

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Bibliographic Details
Main Authors: Marek Freindorf, Elfi Kraka
Format: Article
Language:English
Published: MDPI AG 2022-07-01
Series:Catalysts
Subjects:
Online Access:https://www.mdpi.com/2073-4344/12/7/789