Alkyl-malonate-substituted thiacalix[4]arenes as ligands for bottom-up design of paramagnetic Gd(III)-containing colloids with low cytotoxicity

The present work introduces thiacalix[4]arene adopting 1,3-alternate conformation with alkyl-malonate terminal substituents as ligands for Gd(III) ions. pH-dependent complex formation of Gd(III) ions via alkyl-malonate substituents in aqueous DMSO solutions results in a precipitation. The precipitat...

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Bibliographic Details
Main Authors: Alexey Stepanov, Irek Nizameev, Rustem Amirov, Sofia Kleshnina, Gulshat Khakimullina, Svetlana Solovieva, Alexandra Voloshina, Anastasya Strobykina, Aidar Gubaidullin, Ramil Nugmanov, Asiya Mustafina
Format: Article
Language:English
Published: Elsevier 2020-01-01
Series:Arabian Journal of Chemistry
Online Access:http://www.sciencedirect.com/science/article/pii/S1878535217301053