Substrate specificity in the biomimetic catalytic aerobic oxidation of styrene and cyclohexanone by metalloporphyrins: kinetics and mechanistic study

Substrate specificity is a hallmark of enzymatic catalysis. In this work, the biomimetic catalytic oxidation of styrene and cyclohexanone by iron (III) porphyrins and molecular oxygen was carried out, and remarkable differences in efficiency were observed. The specificity of the substrates for biomi...

Full description

Bibliographic Details
Main Authors: Xian-Tai Zhou, Hong-Bing Ji
Format: Article
Language:English
Published: KeAi Communications Co. Ltd. 2021-06-01
Series:Green Chemical Engineering
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S266695282030025X