Visible-light-driven intramolecular xanthylation of remote unactivated C(sp3)-H bonds

Visible-light-driven intramolecular xanthylation of remote unactivated C(sp3)-H bonds

Visible light-mediated site-specific C(sp3)-H xanthylation of amides has been accomplished using N-xanthylamides. The N-centered radicals generated by light initiation of N-xanthylamide substrates undergo 1,5-hydrogen atom transfer to form benzylic or alkyl radical intermediates under metal- and cat...

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Bibliographic Details
Main Authors: Hang Chen, Yang Zhou, Panpan Lei, Haifeng Wang, Qiongjiao Yan, Roberta Properzi, Wei Wang, Linhai Jing, Fener Chen
Format: Article
Language:English
Published: KeAi Communications Co. Ltd. 2023-11-01
Series:Green Synthesis and Catalysis
Subjects:
C-H functionalization
1,5-Hydrogen atom transfer
Photocatalytic
Site-specific
Xanthylation
Online Access:http://www.sciencedirect.com/science/article/pii/S2666554922000758

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http://www.sciencedirect.com/science/article/pii/S2666554922000758

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