Visible-light-driven intramolecular xanthylation of remote unactivated C(sp3)-H bonds
Visible light-mediated site-specific C(sp3)-H xanthylation of amides has been accomplished using N-xanthylamides. The N-centered radicals generated by light initiation of N-xanthylamide substrates undergo 1,5-hydrogen atom transfer to form benzylic or alkyl radical intermediates under metal- and cat...
Main Authors: | Hang Chen, Yang Zhou, Panpan Lei, Haifeng Wang, Qiongjiao Yan, Roberta Properzi, Wei Wang, Linhai Jing, Fener Chen |
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Format: | Article |
Language: | English |
Published: |
KeAi Communications Co. Ltd.
2023-11-01
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Series: | Green Synthesis and Catalysis |
Subjects: | |
Online Access: | http://www.sciencedirect.com/science/article/pii/S2666554922000758 |
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