Thermal Properties and Dynamic Rheological Characterization of <i>Dioscorea</i> Starch Gels

Yam (<i>Dioscorea</i>. sp.) is an edible starchy tuber with potential for being a commercial source of starch for industrial purposes, but yam starch is underutilized. The dynamic oscillatory and thermal properties of yam starches from sixteen varieties each of <i>Dioscorea. rotund...

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Main Authors: Bolanle Omolara Otegbayo, Abiola Rebecca Tanimola, Julien Ricci, Olivier Gibert
Format: Article
Language:English
Published: MDPI AG 2024-01-01
Series:Gels
Subjects:
Online Access:https://www.mdpi.com/2310-2861/10/1/51
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author Bolanle Omolara Otegbayo
Abiola Rebecca Tanimola
Julien Ricci
Olivier Gibert
author_facet Bolanle Omolara Otegbayo
Abiola Rebecca Tanimola
Julien Ricci
Olivier Gibert
author_sort Bolanle Omolara Otegbayo
collection DOAJ
description Yam (<i>Dioscorea</i>. sp.) is an edible starchy tuber with potential for being a commercial source of starch for industrial purposes, but yam starch is underutilized. The dynamic oscillatory and thermal properties of yam starches from sixteen varieties each of <i>Dioscorea. rotundata</i>, <i>Dioscora. alata</i>, <i>Dioscorea. bulbifera</i> and one variety of <i>Dioscorea. dumetorum</i> from Nigeria were studied to determine their potential for industrial utilization. The storage modulus, loss modulus, damping factor and complex viscosity as a function of frequency (ω) of the <i>dioscorea</i> gels, as well as the onset temperature (<i>T<sub>o</sub></i>), peak gelatinization temperature (<i>T<sub>p</sub></i>), end of gelatinization (<i>T<sub>C</sub></i>), and gelatinization enthalpy of the starches were determined by standard procedures. Results showed that all the <i>dioscorea</i> starches showed a typical elastic behavior with the magnitude of G′ greater than G″ while tan δ < 1 in all varieties. Thus, the starch gels were more elastic than viscous. All the starch gels exhibited shear thinning characteristics and showed frequency (ω) independence characteristics of weak gels. <i>D. rotundata</i> varieties had the lowest ∆<i>H<sub>gel</sub></i>, while <i>D. bulbifera</i> varieties had the highest. The diversity of the visco-elastic and thermal properties of the yam starch gels from different varieties and species can be an advantage in their utilization in both food and non-food industries.
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spelling doaj.art-9d7b64435a7447a58ec8782e430947cb2024-01-26T16:39:53ZengMDPI AGGels2310-28612024-01-011015110.3390/gels10010051Thermal Properties and Dynamic Rheological Characterization of <i>Dioscorea</i> Starch GelsBolanle Omolara Otegbayo0Abiola Rebecca Tanimola1Julien Ricci2Olivier Gibert3Department of Food Science & Technology, Bowen University, P.M.B. 284, Iwo 232102, Osun State, NigeriaDepartment of Food Science & Technology, Bowen University, P.M.B. 284, Iwo 232102, Osun State, NigeriaCIRAD, AGAP Institute, Avenue Agropolis, BP 5035, 34398 Montpellier, FranceCIRAD, AGAP Institute, Avenue Agropolis, BP 5035, 34398 Montpellier, FranceYam (<i>Dioscorea</i>. sp.) is an edible starchy tuber with potential for being a commercial source of starch for industrial purposes, but yam starch is underutilized. The dynamic oscillatory and thermal properties of yam starches from sixteen varieties each of <i>Dioscorea. rotundata</i>, <i>Dioscora. alata</i>, <i>Dioscorea. bulbifera</i> and one variety of <i>Dioscorea. dumetorum</i> from Nigeria were studied to determine their potential for industrial utilization. The storage modulus, loss modulus, damping factor and complex viscosity as a function of frequency (ω) of the <i>dioscorea</i> gels, as well as the onset temperature (<i>T<sub>o</sub></i>), peak gelatinization temperature (<i>T<sub>p</sub></i>), end of gelatinization (<i>T<sub>C</sub></i>), and gelatinization enthalpy of the starches were determined by standard procedures. Results showed that all the <i>dioscorea</i> starches showed a typical elastic behavior with the magnitude of G′ greater than G″ while tan δ < 1 in all varieties. Thus, the starch gels were more elastic than viscous. All the starch gels exhibited shear thinning characteristics and showed frequency (ω) independence characteristics of weak gels. <i>D. rotundata</i> varieties had the lowest ∆<i>H<sub>gel</sub></i>, while <i>D. bulbifera</i> varieties had the highest. The diversity of the visco-elastic and thermal properties of the yam starch gels from different varieties and species can be an advantage in their utilization in both food and non-food industries.https://www.mdpi.com/2310-2861/10/1/51<i>Dioscorea</i>starch gelsdynamic oscillatoryvisco-elasticutilizationgelatinization
spellingShingle Bolanle Omolara Otegbayo
Abiola Rebecca Tanimola
Julien Ricci
Olivier Gibert
Thermal Properties and Dynamic Rheological Characterization of <i>Dioscorea</i> Starch Gels
Gels
<i>Dioscorea</i>
starch gels
dynamic oscillatory
visco-elastic
utilization
gelatinization
title Thermal Properties and Dynamic Rheological Characterization of <i>Dioscorea</i> Starch Gels
title_full Thermal Properties and Dynamic Rheological Characterization of <i>Dioscorea</i> Starch Gels
title_fullStr Thermal Properties and Dynamic Rheological Characterization of <i>Dioscorea</i> Starch Gels
title_full_unstemmed Thermal Properties and Dynamic Rheological Characterization of <i>Dioscorea</i> Starch Gels
title_short Thermal Properties and Dynamic Rheological Characterization of <i>Dioscorea</i> Starch Gels
title_sort thermal properties and dynamic rheological characterization of i dioscorea i starch gels
topic <i>Dioscorea</i>
starch gels
dynamic oscillatory
visco-elastic
utilization
gelatinization
url https://www.mdpi.com/2310-2861/10/1/51
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AT julienricci thermalpropertiesanddynamicrheologicalcharacterizationofidioscoreaistarchgels
AT oliviergibert thermalpropertiesanddynamicrheologicalcharacterizationofidioscoreaistarchgels