Modification of Cooperativity and Critical Temperatures on a Hofmann-Like Template Structure by Modular Substituent

In a series of Hofmann-like spin crossover complexes, two new compounds, {Fe(3-F-4-Methyl-py)2[Au(CN)2]2} (1) and {Fe(3-Methyl-py)2[Au(CN)2]2} (2) (py = pyridine) are described. The series maintains a uniform 2-dimentional (2-D) layer structure of {Fe[Au(CN)2]2}. The layers are combined with another...

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Bibliographic Details
Main Authors: Takashi Kosone, Takeshi Kawasaki, Itaru Tomori, Jun Okabayashi, Takafumi Kitazawa
Format: Article
Language:English
Published: MDPI AG 2017-08-01
Series:Inorganics
Subjects:
Online Access:https://www.mdpi.com/2304-6740/5/3/55