SYNTHESIS AND PHOTOOXYGENATION OF THE METHYL ESTER OF 11-HOMODRIM-6,8(9)-DIENE-12-OIC ACID
Starting with the methyl 11-homodrim-8-ene-7-oxo-12-oate a two steps synthesis of methyl-11-homodrim-6,8(9)- diene-12-oate was accomplished in 87% overall yield, which on photooxygenation in the presence of tetraphenylporphyrin gave a mixture of methyl esters of 11-homodrim-7-ene-6α,9α-peroxy-12-o...
| Main Author: | |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Academy of Sciences of Moldova, Institute of Chemistry
2011-12-01
|
| Series: | Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry |
| Subjects: | |
| Online Access: | http://www.cjm.asm.md/sites/default/files/article_files/Biriac%20017%20.pdf |