Area-Selective Growth of Zinc Oxide Nanowire Arrays for Piezoelectric Energy Harvesting

In this work, we present the area-selective growth of zinc oxide nanowire (NW) arrays on patterned surfaces of a silicon (Si) substrate for a piezoelectric nanogenerator (PENG). ZnO NW arrays were selectively grown on patterned surfaces of a Si substrate using a devised microelectromechanical system...

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Main Authors: Frank Eric Boye Anang, Xuanwei Wei, Jiushuai Xu, Markys Cain, Zhi Li, Uwe Brand, Erwin Peiner
Format: Article
Language:English
Published: MDPI AG 2024-02-01
Series:Micromachines
Subjects:
Online Access:https://www.mdpi.com/2072-666X/15/2/261
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author Frank Eric Boye Anang
Xuanwei Wei
Jiushuai Xu
Markys Cain
Zhi Li
Uwe Brand
Erwin Peiner
author_facet Frank Eric Boye Anang
Xuanwei Wei
Jiushuai Xu
Markys Cain
Zhi Li
Uwe Brand
Erwin Peiner
author_sort Frank Eric Boye Anang
collection DOAJ
description In this work, we present the area-selective growth of zinc oxide nanowire (NW) arrays on patterned surfaces of a silicon (Si) substrate for a piezoelectric nanogenerator (PENG). ZnO NW arrays were selectively grown on patterned surfaces of a Si substrate using a devised microelectromechanical system (MEMS)-compatible chemical bath deposition (CBD) method. The fabricated devices measured a maximum peak output voltage of ~7.9 mV when a mass of 91.5 g was repeatedly manually placed on them. Finite element modeling (FEM) of a single NW using COMSOL Multiphysics at an applied axial force of 0.9 nN, which corresponded to the experimental condition, resulted in a voltage potential of −6.5 mV. The process repeated with the same pattern design using a layer of SU-8 polymer on the NWs yielded a much higher maximum peak output voltage of ~21.6 mV and a corresponding peak power density of 0.22 µW/cm<sup>3</sup>, independent of the size of the NW array. The mean values of the measured output voltage and FEM showed good agreement and a nearly linear dependence on the applied force on a 3 × 3 µm<sup>2</sup> NW array area in the range of 20 to 90 nN.
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spelling doaj.art-9e3a00fbf7424eefa9080d65743600252024-02-23T15:27:49ZengMDPI AGMicromachines2072-666X2024-02-0115226110.3390/mi15020261Area-Selective Growth of Zinc Oxide Nanowire Arrays for Piezoelectric Energy HarvestingFrank Eric Boye Anang0Xuanwei Wei1Jiushuai Xu2Markys Cain3Zhi Li4Uwe Brand5Erwin Peiner6Institute of Semiconductor Technology, TU Braunschweig, 38104 Braunschweig, GermanyInstitute of Semiconductor Technology, TU Braunschweig, 38104 Braunschweig, GermanyInstitute of Semiconductor Technology, TU Braunschweig, 38104 Braunschweig, GermanyElectrosciences Ltd., Farnham, Surrey GU9 9QT, UKSurface Metrology Department, Physikalisch-Technische Bundesanstalt (PTB), 38116 Braunschweig, GermanySurface Metrology Department, Physikalisch-Technische Bundesanstalt (PTB), 38116 Braunschweig, GermanyInstitute of Semiconductor Technology, TU Braunschweig, 38104 Braunschweig, GermanyIn this work, we present the area-selective growth of zinc oxide nanowire (NW) arrays on patterned surfaces of a silicon (Si) substrate for a piezoelectric nanogenerator (PENG). ZnO NW arrays were selectively grown on patterned surfaces of a Si substrate using a devised microelectromechanical system (MEMS)-compatible chemical bath deposition (CBD) method. The fabricated devices measured a maximum peak output voltage of ~7.9 mV when a mass of 91.5 g was repeatedly manually placed on them. Finite element modeling (FEM) of a single NW using COMSOL Multiphysics at an applied axial force of 0.9 nN, which corresponded to the experimental condition, resulted in a voltage potential of −6.5 mV. The process repeated with the same pattern design using a layer of SU-8 polymer on the NWs yielded a much higher maximum peak output voltage of ~21.6 mV and a corresponding peak power density of 0.22 µW/cm<sup>3</sup>, independent of the size of the NW array. The mean values of the measured output voltage and FEM showed good agreement and a nearly linear dependence on the applied force on a 3 × 3 µm<sup>2</sup> NW array area in the range of 20 to 90 nN.https://www.mdpi.com/2072-666X/15/2/261area-selective growthZnO nanowire arraysMEMSCBD growthSU-8 polymerPENG
spellingShingle Frank Eric Boye Anang
Xuanwei Wei
Jiushuai Xu
Markys Cain
Zhi Li
Uwe Brand
Erwin Peiner
Area-Selective Growth of Zinc Oxide Nanowire Arrays for Piezoelectric Energy Harvesting
Micromachines
area-selective growth
ZnO nanowire arrays
MEMS
CBD growth
SU-8 polymer
PENG
title Area-Selective Growth of Zinc Oxide Nanowire Arrays for Piezoelectric Energy Harvesting
title_full Area-Selective Growth of Zinc Oxide Nanowire Arrays for Piezoelectric Energy Harvesting
title_fullStr Area-Selective Growth of Zinc Oxide Nanowire Arrays for Piezoelectric Energy Harvesting
title_full_unstemmed Area-Selective Growth of Zinc Oxide Nanowire Arrays for Piezoelectric Energy Harvesting
title_short Area-Selective Growth of Zinc Oxide Nanowire Arrays for Piezoelectric Energy Harvesting
title_sort area selective growth of zinc oxide nanowire arrays for piezoelectric energy harvesting
topic area-selective growth
ZnO nanowire arrays
MEMS
CBD growth
SU-8 polymer
PENG
url https://www.mdpi.com/2072-666X/15/2/261
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