Urea–hydrogen peroxide prompted the selective and controlled oxidation of thioglycosides into sulfoxides and sulfones

Urea–hydrogen peroxide prompted the selective and controlled oxidation of thioglycosides into sulfoxides and sulfones

A practical method for the selective and controlled oxidation of thioglycosides to corresponding glycosyl sulfoxides and sulfones is reported using urea–hydrogen peroxide (UHP). A wide range of glycosyl sulfoxides are selectively achieved using 1.5 equiv of UHP at 60 °C while corresponding sulfones...

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Bibliographic Details
Main Authors: Adesh Kumar Singh, Varsha Tiwari, Kunj Bihari Mishra, Surabhi Gupta, Jeyakumar Kandasamy
Format: Article
Language:English
Published: Beilstein-Institut 2017-06-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
monosaccharides
oxidation
sulfones
sulfoxides
thioglycosides
urea–hydrogen peroxide
Online Access:https://doi.org/10.3762/bjoc.13.113

Internet

https://doi.org/10.3762/bjoc.13.113

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