Ab initio study of the mechanism of forming a spiro-Si-heterocyclic ring compound involving Ge from H2Ge=Si: and acetaldehyde

The H2Ge=Si: and its derivatives(X2Ge=Si:, X = H, Me, F, Cl, Br, Ph, Ar……) is a new species. Its cycloaddition reactions is a new area for the study of silylene chemistry. The mechanism of the cycloaddition reaction between singlet H2Ge=Si: and acetaldehyde has been investigated with MP2/6-...

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Bibliographic Details
Main Authors: Lu Xiuhui, Ming Jingjing
Format: Article
Language:English
Published: Serbian Chemical Society 2016-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/0352-5139/2016/0352-51391600014L.pdf