Ammonothermal Synthesis, X‐Ray and Time‐of‐Flight Neutron Crystal‐Structure Determination, and Vibrational Properties of Barium Guanidinate, Ba(CN3H4)2

Ammonothermal Synthesis, X‐Ray and Time‐of‐Flight Neutron Crystal‐Structure Determination, and Vibrational Properties of Barium Guanidinate, Ba(CN3H4)2

Abstract We report the crystal structure of Ba(CN3H4)2 as synthesized from liquid ammonia. Structure solution based on X‐ray diffraction data suffers from a severe pseudo‐tetragonal problem due to extreme scattering contrast, so the true monoclinic symmetry is detectable only from neutron powder dif...

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Bibliographic Details
Main Authors: Dr. Sebastian Benz, Dr. Ronja Missong, George Ogutu, Dr. Ralf P. Stoffel, Prof. Dr. Ulli Englert, Dr. Shuki Torii, Dr. Ping Miao, Prof. Dr. Takashi Kamiyama, Prof. Dr. Richard Dronskowski
Format: Article
Language:English
Published: Wiley-VCH 2019-03-01
Series:ChemistryOpen
Subjects:
barium
X-ray diffraction
neutron diffraction
vibrational spectroscopy
density-functional theory
Online Access:https://doi.org/10.1002/open.201900068

Internet

https://doi.org/10.1002/open.201900068

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