The role of sulfonate groups and hydrogen bonding in the proton conductivity of two coordination networks

The role of sulfonate groups and hydrogen bonding in the proton conductivity of two coordination networks

The proton conductivity of two coordination networks, [Mg(H2O)2(H3L)]·H2O and [Pb2(HL)]·H2O (H5L = (H2O3PCH2)2-NCH2-C6H4-SO3H), is investigated by AC impedance spectroscopy. Both materials contain the same phosphonato-sulfonate linker molecule, but have clearly different crystal structures, which ha...

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Bibliographic Details
Main Authors: Ali Javed, Felix Steinke, Stephan Wöhlbrandt, Hana Bunzen, Norbert Stock, Michael Tiemann
Format: Article
Language:English
Published: Beilstein-Institut 2022-05-01
Series:Beilstein Journal of Nanotechnology
Subjects:
coordination network
coordination polymer
impedance spectroscopy
metal-organic framework
proton conductivity
Online Access:https://doi.org/10.3762/bjnano.13.36

Internet

https://doi.org/10.3762/bjnano.13.36

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