A Comprehensive Analysis of the Metal–Nitrile Bonding in an Organo-Diiron System

A Comprehensive Analysis of the Metal–Nitrile Bonding in an Organo-Diiron System

Nitriles (N≡CR) are ubiquitous in coordination chemistry, yet literature studies on metal–nitrile bonding based on a multi-technique approach are rare. We selected an easily-available di-organoiron framework, containing both π-acceptor (CO, aminocarbyne) and donor (Cp = η<sup>5</sup>−C&l...

Full description

Bibliographic Details
Main Authors: Giulio Bresciani, Lorenzo Biancalana, Guido Pampaloni, Stefano Zacchini, Gianluca Ciancaleoni, Fabio Marchetti
Format: Article
Language:English
Published: MDPI AG 2021-11-01
Series:Molecules
Subjects:
coordination chemistry
nitrile ligand
metal–nitrile bonding
π-back-donation
diiron complexes
DFT calculations
Online Access:https://www.mdpi.com/1420-3049/26/23/7088

Internet

https://www.mdpi.com/1420-3049/26/23/7088

Similar Items