Synthesis of Dense 1,2,3-Triazole Oligomers Consisting Preferentially of 1,5-Disubstituted Units via Ruthenium(II)-Catalyzed Azide–Alkyne Cycloaddition

Synthesis of Dense 1,2,3-Triazole Oligomers Consisting Preferentially of 1,5-Disubstituted Units via Ruthenium(II)-Catalyzed Azide–Alkyne Cycloaddition

Ruthenium(II)-catalyzed azide–alkyne cycloaddition (RuAAC) polymerization of <i>t</i>-butyl 4-azido-5-hexynoate (tBuAH), i.e., a heterobifunctional monomer carrying azide and alkyne moieties, was investigated in this study. RuAAC of the monofunctional precursors of tBuAH yielded a dimer...

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Bibliographic Details
Main Authors: Ryoichi Taguchi, Masaki Nakahata, Yuri Kamon, Akihito Hashidzume
Format: Article
Language:English
Published: MDPI AG 2023-05-01
Series:Polymers
Subjects:
click chemistry
ruthenium(II)-catalyzed azide–alkyne cycloaddition
1,5-disubstituted 1,2,3-triazole
dense 1,2,3-triazole polymer
Online Access:https://www.mdpi.com/2073-4360/15/9/2199

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https://www.mdpi.com/2073-4360/15/9/2199

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