Synthesis and Properties of New Molecule-Based Magnets Containing Mn(II), Cu(II) and Nitronyl Nitroxide Radical Cation

Synthesis and Properties of New Molecule-Based Magnets Containing Mn(II), Cu(II) and Nitronyl Nitroxide Radical Cation

In this work, we describe the synthesis of two new copper(II) compounds, (Pr-Rad)2 [Cu(opba)].H2O (1) and (Bu-Rad)2[Cu(opba)].2H2O (2) where opba stands for ortho-phenylenebis(oxamato) and RRad+ are nitronyl nitroxide radical cations. From 1 and 2, two new molecule-based magnets [Pr-Rad]2[Mn2{Cu(opb...

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Bibliographic Details
Main Authors: Vaz Maria G. F., Knobel Marcelo, Speziali Nivaldo L., Moreira Alexandre M., Alcântara Antônio F. C., Stumpf Humberto O.
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2002-01-01
Series:Journal of the Brazilian Chemical Society
Subjects:
supramolecular chemistry
molecule-based magnets
molecular materials
catenanes
ferrimagnetism
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000200009

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http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000200009

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