Transition-metal-free trifluoromethylthiolation–acylation of arynes by insertion into the C–S bonds

An efficient procedure to access to ortho-SCF3 substituted benzophenones from arynes and trifluoromethylthioesters has been developed under transition-metal free conditions. This difunctionalization process involves the first insertion of arynes into the C–S σ-bonds to achieve vicinal trifluoromethy...

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Bibliographic Details
Main Authors: Chengyao Kimmy Cao, Evgeny Tretyakov, Chao Chen
Format: Article
Language:English
Published: KeAi Communications Co. Ltd. 2021-02-01
Series:Green Synthesis and Catalysis
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666554920300533