Crystal structure of bis(η2-ethylene)(η5-pentamethylcyclopentadienyl)cobalt

The title compound, [Co(C10H15)(C2H4)2], was prepared by Na/Hg reduction of [Co2(C10H15)2(μ-Cl)2] in THF under an ethylene atmosphere and crystallized from pentane at 193 K. The Co—C(olefin) bonds have an average length of 2.022 (2) Å, while the Co—C(pentadienyl) bonds average 2.103 (19) Å. The olef...

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Manylion Llyfryddiaeth
Prif Awduron: Chandika D. Ramful, Katherine N. Robertson, Kai E. O. Ylijoki
Fformat: Erthygl
Iaith:English
Cyhoeddwyd: International Union of Crystallography 2016-09-01
Cyfres:Acta Crystallographica Section E: Crystallographic Communications
Pynciau:
Mynediad Ar-lein:http://scripts.iucr.org/cgi-bin/paper?S2056989016012822