An Efficient Entry to Planar Chiral Organometallic Complexes via Pd-Catalyzed Asymmetric Hydrogenolysis

An Efficient Entry to Planar Chiral Organometallic Complexes via Pd-Catalyzed Asymmetric Hydrogenolysis

Planar chiral chromium- and ruthenium-based arene complexes were prepared with high levels of enantioselectivity via a Pd-catalyzed asymmetric hydrogenolysis reaction using a bulky chiral phosphoramidite ligand. Key elements for the efficiency of the process are the use of DABCO as borane-...

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Bibliographic Details
Main Authors: Audrey Mercier, Wee Chuan Yeo, Xavier Urbaneja, E. Peter Kündig
Format: Article
Language:deu
Published: Swiss Chemical Society 2010-03-01
Series:CHIMIA
Subjects:
Catalytic desymmetrization
Chromium
Hydrogenolysis
Planar chirality
Ruthenium
Online Access:https://www.chimia.ch/chimia/article/view/4824

Internet

https://www.chimia.ch/chimia/article/view/4824

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