A five-coordinate cobalt bis(dithiolene)–phosphine complex [Co(pdt)2(PTA)] (pdt = phenyldithiolene; PTA = 1,3,5-triaza-7-phosphaadamantane)

A five-coordinate cobalt bis(dithiolene)–phosphine complex [Co(pdt)2(PTA)] (pdt = phenyldithiolene; PTA = 1,3,5-triaza-7-phosphaadamantane)

The title compound, bis(1,2-diphenyl-2-sulfanylideneethanethiolato-κ2S,S′)(1,3,5-triaza-7-phosphaadamantane-κP)cobalt(II) dichloromethane hemisolvate, [Co(pdt)2(PTA)]·0.5C2H4Cl2 or [Co(C14H10S2)2(C6H12N3P)]·0.5C2H4Cl2, contains two phenyldithiolene (pdt) ligands and a 1,3,5-triaza-7-phosphaadamantan...

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Bibliographic Details
Main Authors: DaShawn Williams, Jacob P. Brannon, Perumalreddy Chandrasekaran, S. Chantal E. Stieber
Format: Article
Language:English
Published: International Union of Crystallography 2020-05-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
cobalt complex
dithiolene
redox-active
non-innocent ligand
pta ligand
crystal structure
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989020005447

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http://scripts.iucr.org/cgi-bin/paper?S2056989020005447

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