Dissociative Electron Transfer to Diphenyl-Substituted Bicyclic Endoperoxides: The Effect of Molecular Structure on the Reactivity of Distonic Radical Anions and Determination of Thermochemical Parameters

Dissociative Electron Transfer to Diphenyl-Substituted Bicyclic Endoperoxides: The Effect of Molecular Structure on the Reactivity of Distonic Radical Anions and Determination of Thermochemical Parameters

The heterogeneous electron transfer reduction of the bicyclic endoperoxide 1,4-diphenyl-2,3-dioxabicyclo[2.2.1]hept-5-ene (4) was investigated in N,N-dimethylformamide  at a glassy carbon electrode. The endoperoxide reacts by a concerted dissociative ET mechanism resulting in reduction of the O-O bo...

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Bibliographic Details
Main Authors: David C. Magri, Mark S. Workentin
Format: Article
Language:English
Published: MDPI AG 2014-08-01
Series:Molecules
Subjects:
dissociative electron transfer
distonic radical ion
endoperoxide
convolution analysis
electrode interface
cyclic voltammetry
Online Access:http://www.mdpi.com/1420-3049/19/8/11999

Internet

http://www.mdpi.com/1420-3049/19/8/11999

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