An isolable, chelating bis[cyclic (alkyl)(amino)carbene] stabilizes a strongly bent, dicoordinate Ni(0) complex

Abstract Chelating ligands have had a tremendous impact in coordination chemistry and catalysis. Notwithstanding their success as strongly σ-donating and π-accepting ligands, to date no chelating bis[cyclic (alkyl)(amino)carbenes] have been reported. Herein, we describe a chelating, C 2-symmetric bi...

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Bibliographic Details
Main Authors: Braulio M. Puerta Lombardi, Morgan R. Faas, Daniel West, Roope A. Suvinen, Heikki M. Tuononen, Roland Roesler
Format: Article
Language:English
Published: Nature Portfolio 2024-04-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-024-47036-7